(Acetyl-acetonato-κO,O')(2-bromo-4-chloro-6-{[2-(dimethyl-amino)-ethyl-imino]-meth-yl}phenolato-κN,N',O)oxidovanadium(IV)

Fu-Ming Wang

doi:10.1107/S1600536811015406

(Acetyl-acetonato-κO,O')(2-bromo-4-chloro-6-{[2-(dimethyl-amino)-ethyl-imino]-meth-yl}phenolato-κN,N',O)oxidovanadium(IV)

Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m650. doi: 10.1107/S1600536811015406. Epub 2011 Apr 29.

Author

Fu-Ming Wang¹

Affiliation

¹ Department of Chemistry, Dezhou University, Dezhou Shandong 253023, People's Republic of China.

Abstract

The V(IV) atom in the title complex, [V(C(11)H(13)BrClN(2)O)(C(5)H(7)O(2))O], is six-coordinated by one phenolate O, one imino N and one amino N atom of the tridentate anionic Schiff base ligand, by one oxide O atom, and by two O atoms of an acetyl-acetonate anion, forming a distorted cis-VN(2)O(4) octa-hedral coordination geometry. The deviation of the V atom from the plane defined by the three donor atoms of the Schiff base ligand and one O atom of the acetyl-acetone ligand towards the oxide O atom is 0.256 (2) Å.