Optical properties of GaN nanorods grown by molecular-beam epitaxy; dependence on growth time

Nanotechnology. 2006 Feb 28;17(4):952-5. doi: 10.1088/0957-4484/17/4/019. Epub 2006 Jan 30.

Abstract

The growth and optical properties of GaN nanorods grown on Si(111) substrates by rf plasma assisted molecular-beam epitaxy are investigated by means of field emission scanning electron microscopy and photoluminescence measurements as a function of growth time. It is clearly demonstrated that the rate of growth of the nanorod diameter starts to increase after ∼90 min because of the coalescence of neighbouring nanorods. And the optical properties of the samples grown at a high growth rate are dramatically changed due to induced defects. The critical diameter for defect-free GaN nanorods is determined as below ∼140 nm under N-rich conditions.