Solvothermal growth of a ruthenium metal-organic framework featuring HKUST-1 structure type as thin films on oxide surfaces

Olesia Kozachuk; Kirill Yusenko; Heshmat Noei; Yuemin Wang; Stephan Walleck; Thorsten Glaser; Roland A Fischer

doi:10.1039/c1cc11107h

Solvothermal growth of a ruthenium metal-organic framework featuring HKUST-1 structure type as thin films on oxide surfaces

Chem Commun (Camb). 2011 Aug 14;47(30):8509-11. doi: 10.1039/c1cc11107h. Epub 2011 Jun 29.

Authors

Olesia Kozachuk¹, Kirill Yusenko, Heshmat Noei, Yuemin Wang, Stephan Walleck, Thorsten Glaser, Roland A Fischer

Affiliation

¹ Inorganic Chemistry II-Organometallics and Materials Chemistry, Ruhr-University Bochum, Universitätsstrasse 150, 44801 Bochum, Germany.

PMID: 21716991
DOI: 10.1039/c1cc11107h

Abstract

Phase-pure crystalline thin films of a mixed-valence Ru(2)(II,III) metal-organic framework with 1,3,5-benzenetricarboxylate (btc) as a linker were solvothermally grown on amorphous alumina and silica surfaces. Based on the Rietveld refinement, the structure of Ru-MOF was assigned to be analogous to [Cu(3)(btc)(2)] (HKUST-1).