A 3D Cu(II) coordination framework with μ4-/μ2-oxalato anions and a bent dipyridyl coligand: unique zeolite-type NiP2 topological network and magnetic properties

Miao Du; Zhi-Hui Zhang; Cheng-Peng Li; Jordi Ribas-Ariño; Núria Aliaga-Alcalde; Joan Ribas

doi:10.1021/ic200711e

A 3D Cu(II) coordination framework with μ4-/μ2-oxalato anions and a bent dipyridyl coligand: unique zeolite-type NiP2 topological network and magnetic properties

Inorg Chem. 2011 Aug 1;50(15):6850-2. doi: 10.1021/ic200711e. Epub 2011 Jun 23.

Authors

Miao Du¹, Zhi-Hui Zhang, Cheng-Peng Li, Jordi Ribas-Ariño, Núria Aliaga-Alcalde, Joan Ribas

Affiliation

¹ College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecule, Tianjin Normal University, Tianjin 300387, People's Republic of China. dumiao@public.tpt.tj.cn

PMID: 21699173
DOI: 10.1021/ic200711e

Abstract

The reaction of copper(II) nitrate, oxamide, and an angular bridging ligand 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (4-bpo) under hydrothermal conditions affords a 3D pillared-layer coordination framework {[Cu(2)(4-bpo)(ox)(2)](H(2)O)(4)}(n) (1) (ox = oxalate), featuring the unique zeolite-type NiP(2) network and interesting properties.