Application of parametric equations of motion to study the laser induced multiphoton dissociation of H2+ in intense laser field

J Chem Phys. 2011 Jun 14;134(22):224309. doi: 10.1063/1.3598516.

Abstract

We have applied parametric equations of motion (PEM) to study photodissociation dynamics of H(2)(+). The resonances are extracted using smooth exterior scaling method. This is the first application of PEM to non-Hermitian Hamiltonian that includes resonances and the continuum. Here, we have studied how the different resonance states behave with respect to the change in field amplitude. The advantage of this method is that one can easily trace the different states that are changing as the field parameter changes.