Solvent-dependent supramolecular assemblies of π-conjugated anion-responsive acyclic oligopyrroles

Chem Commun (Camb). 2011 Jul 21;47(27):7620-2. doi: 10.1039/c1cc12827b. Epub 2011 Jun 10.

Abstract

Amide-attached pyrrole-based π-conjugated anion receptors showed solvent-dependent assembled modes such as H-aggregates that were soluble in octane and highly organized structures that provided supramolecular gels in CH(2)Cl(2) and 1,4-dioxane in the absence of π-π stacking.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amides / chemistry*
  • Anions / chemistry
  • Dioxanes / chemistry
  • Gels / chemistry
  • Pyrroles / chemistry*
  • Solvents / chemistry

Substances

  • Amides
  • Anions
  • Dioxanes
  • Gels
  • Pyrroles
  • Solvents
  • 1,4-dioxane