Highly efficient visible light TiO2 photocatalyst prepared by sol-gel method at temperatures lower than 300°C

Abstract

Highly efficient visible light TiO(2) photocatalyst was prepared by the sol-gel method at lower temperature (≤ 300°C), and characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier-transform infrared spectroscopy (FTIR), UV-vis diffuse reflectance spectroscopy (UV-vis DRS), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy and differential scanning calorimetry-thermogravimetric analysis (DSC-TGA). The effects of the heat treatment temperature and time of the as-prepared TiO(2) on its visible light photocatalytic activity were investigated by monitoring the degradation of methyl orange solution under visible light irradiation (wavelength ≥ 400 nm). Results show that the as-prepared TiO(2) nanoparticles possess an anatase phase and mesoporous structure with carbon self-doping and visible photosensitive organic groups. The visible light photocatalytic activity of the as-prepared TiO(2) is greatly higher than those of the commercial TiO(2) (P-25) and other visible photocatalysts reported in literature (such as PPy/TiO(2), P3HT/TiO(2), PANI/TiO(2), N-TiO(2) and Fe(3+)-TiO(2)) and its photocatalytic stability is excellent. The reasons for improving the visible light photocatalytic activity of the as-prepared TiO(2) can be explained by carbon self-doping and a large amount of visible photosensitive groups existing in the as-prepared TiO(2). The apparent optical thickness (τ(app)), local volumetric rate of photo absorption (LVRPA) and kinetic constant (k(T)) of the photodegradation system were calculated.