Triphenylene-fused porphyrins

Org Lett. 2011 Jun 17;13(12):3020-3. doi: 10.1021/ol200853g. Epub 2011 May 23.

Abstract

Triphenylene has been successfully fused to the porphyrin periphery through a convenient oxidative ring-closure reaction. Bistriphenylene-fused porphyrins and a dibenzo[fg,op]tetracene-fused porphyrin have also been obtained using a similar approach. These π-extended porphyrins exhibited broadened and bathochromic shifted UV-vis absorptions.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Catalysis
  • Chrysenes / chemical synthesis*
  • Chrysenes / chemistry
  • Models, Molecular*
  • Molecular Structure
  • Palladium / chemistry
  • Porphyrins / chemical synthesis*
  • Porphyrins / chemistry
  • Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization

Substances

  • Chrysenes
  • Porphyrins
  • triphenylene
  • Palladium