Abstract
Triphenylene has been successfully fused to the porphyrin periphery through a convenient oxidative ring-closure reaction. Bistriphenylene-fused porphyrins and a dibenzo[fg,op]tetracene-fused porphyrin have also been obtained using a similar approach. These π-extended porphyrins exhibited broadened and bathochromic shifted UV-vis absorptions.
© 2011 American Chemical Society
Publication types
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Catalysis
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Chrysenes / chemical synthesis*
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Chrysenes / chemistry
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Models, Molecular*
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Molecular Structure
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Palladium / chemistry
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Porphyrins / chemical synthesis*
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Porphyrins / chemistry
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Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization
Substances
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Chrysenes
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Porphyrins
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triphenylene
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Palladium