Chloridodimeth-yl(thio-semi-carbazide)tin(IV) chloride

Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 2;66(Pt 11):m1353. doi: 10.1107/S1600536810038705.

Abstract

In the title salt, [Sn(CH(3))(2)Cl(CH(4)N(3)S)]Cl, the Sn(IV) atom is five-coordinated in a distorted trigonal-bipyramidal geometry with two methyl groups and one S atom in the equatorial plane, and one N atom and one Cl atom occupying the apical positions. In the crystal, mol-ecules are linked by inter-molecular N-H⋯S hydrogen bonds with set graph-motif C(4) along [010]. N-H⋯ Cl hydrogen bonds with graph-set motif D(2) and D(3) (3)(10) link cations and anions.