(Methanol-κO)(2-methyl-3-nitro-benzoato-κO)triphenyl-tin(IV)

Acta Crystallogr Sect E Struct Rep Online. 2010 Aug 28;66(Pt 9):m1164. doi: 10.1107/S1600536810033623.

Abstract

The five-coordinate Sn atom in the title compound, [Sn(C(6)H(5))(3)(C(8)H(6)NO(4))(CH(3)OH)], exists in a trans-C(3)SnO(2) trigonal-bipyramidal coordination polyhedron of which the O atoms of the methanol mol-ecule and carboxyl-ate group occupy the apical sites. In the crystal, adjacent mol-ecules are linked by inter-molecular O-H⋯O inter-actions, generating a helical hydrogen-bonded chain running along the b axis.