Dibut-yl{N'-[1-(5-chloro-2-oxidophenyl-κO)ethyl-idene]-3-hy-droxy-2-naphtho-hydrazidato-κN',O}tin(IV)

See Mun Lee; Hapipah Mohd Ali; Kong Mun Lo

doi:10.1107/S1600536810021896

Dibut-yl{N'-[1-(5-chloro-2-oxidophenyl-κO)ethyl-idene]-3-hy-droxy-2-naphtho-hydrazidato-κN',O}tin(IV)

Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):m803. doi: 10.1107/S1600536810021896.

Authors

See Mun Lee¹, Hapipah Mohd Ali, Kong Mun Lo

Affiliation

¹ Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

Abstract

The five-coordinate Sn(IV) atoms in the two crystallographically independent mol-ecules of the title compound, [Sn(C(4)H(9))(2)(C(19)H(13)ClN(2)O(3))], are in distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination environments. The tridentate dianion of the Schiff base, N'-[1-(5-chloro-2-oxidophen-yl)ethyl-idene]-3-hy-droxy-2-naphtho-hydrazide, displays inter-molecular O-H⋯N hydrogen bonding, which stabilizes the overall compound.