Poly[(μ(6)-benzene-1,3,5-tricarboxyl-ato-κO:O:O:O:O:O)tris-(N,N-dimethyl-formamide-κO)tris-(μ(3)-formato-κO:O')trimagnesium(II)]

Chun-Ting Yeh; Hsin-Kuan Liu; Chia-Jing Lin; Chia-Her Lin

doi:10.1107/S1600536810035907

Poly[(μ(6)-benzene-1,3,5-tricarboxyl-ato-κO:O:O:O:O:O)tris-(N,N-dimethyl-formamide-κO)tris-(μ(3)-formato-κO:O')trimagnesium(II)]

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 25;66(Pt 10):m1289. doi: 10.1107/S1600536810035907.

Authors

Chun-Ting Yeh¹, Hsin-Kuan Liu, Chia-Jing Lin, Chia-Her Lin

Affiliation

¹ Department of Chemistry, Chung-Yuan Christian University, Chung-Li 320, Taiwan.

Abstract

The title complex, [Mg(3)(CHO(2))(3)(C(9)H(3)O(6))(C(3)H(7)NO)(3)](n), exhib-its a two-dimensional structure parallel to (001), which is built up from the Mg(II) atoms and bridging carboxyl-ate ligands (3 symmetry). The Mg(II) atom is six-coordinated by one O atom from a dimethyl-formamide mol-ecule, two O atoms from two μ(6)-benzene-1,3,5-tricarboxyl-ate ligands and three O atoms from three μ(3)-formate ligands in a distorted octa-hedral geometry.