Poly[μ(2)-chlorido-(μ(2)-3H-1,3,4-thia-diazo-lium-2-thiol-ato-κS:S)silver(I)]

Jian-Ge Wang; Jian-Hua Qin; Pu-Zhou Hu

doi:10.1107/S1600536809012975

Poly[μ(2)-chlorido-(μ(2)-3H-1,3,4-thia-diazo-lium-2-thiol-ato-κS:S)silver(I)]

Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 10;65(Pt 5):m507. doi: 10.1107/S1600536809012975.

Authors

Jian-Ge Wang¹, Jian-Hua Qin, Pu-Zhou Hu

Affiliation

¹ College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, People's Republic of China.

Abstract

In the title compound, [AgCl(C(2)H(2)N(2)S(2))](n), the Ag(I) ion has a distorted tetra-hedral geometry, defined by two S atoms of two symmetry-related 1,3,4-thia-diazo-lium-2-thiol-ate ligands and two chloride ions. The Ag(I) ions are bridged into a two-dimensional network parallel to the ab plane by chloride ions and thia-diazole ligands. In the network, the Ag(I) ions are separated by 4.0316 (12) Å along the a axis and by 4.8822 (13) Å along the b axis. N-H⋯Cl hydrogen bonds are observed within the network.