{Bis[2-(diphenyl-phosphino)phen-yl] ether-κP:P'}(dimethyl 2,2'-biphenyl-4,4'-dicarboxyl-ate-κN:N')copper(I) hexa-fluorido-phosphate acetonitrile solvate

Ai-Guo Yu; Ming Zhang; Guang-Di Yang; Ling Ye; Yu-Guang Ma

doi:10.1107/S1600536809024982

{Bis[2-(diphenyl-phosphino)phen-yl] ether-κP:P'}(dimethyl 2,2'-biphenyl-4,4'-dicarboxyl-ate-κN:N')copper(I) hexa-fluorido-phosphate acetonitrile solvate

Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 4;65(Pt 8):m875. doi: 10.1107/S1600536809024982.

Authors

Ai-Guo Yu¹, Ming Zhang, Guang-Di Yang, Ling Ye, Yu-Guang Ma

Affiliation

¹ State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, People's Republic of China.

Abstract

In the title compound, [Cu(C(14)H(12)N(2)O(4))(C(36)H(28)OP(2))]PF(6)·CH(3)CN, the Cu(I) ion is coordinated by two N atoms from the dimethyl 2,2'-biphenyl-4,4'-dicarboxyl-ate ligand and two P atoms from the bis-[2-(diphenyl-phosphino)phen-yl] ether ligand in a distorted tetra-hedral environment. In the cation, the short distance of 3.870 (4) Å between the centroids of the benzene and phenyl rings suggests the existence of intra-molecular π-π inter-actions.