Bis[4-(2-hydroxy-benzyl-ideneamino)benzoato-κO]tetrakis-(methanol-κO)manganese(II)

Acta Crystallogr Sect E Struct Rep Online. 2009 May 14;65(Pt 6):m634. doi: 10.1107/S160053680901681X.

Abstract

In the title mononuclear complex, [Mn(C(14)H(10)NO(3))(2)(CH(3)OH)(4)], the Mn(II) atom, lying on an inversion centre, exhibits a distorted octa-hedral geometry, defined by two O atoms from two monodentate ligands and four O atoms from four methanol mol-ecules. The crystal structure involves intra-molecular O-H⋯N and O-H⋯O and inter-molecular O-H⋯O hydrogen bonds.