3-exo-Chloro-8-oxabicyclo-[3.2.1]oct-6-ene-2,4-diol chloro-form 0.33-solvate

Viktor A Tafeenko; Leonid A Aslanov; Marina V Proskurnina; Sergei E Sosonyuk; Dmitrii A Khlevin

doi:10.1107/S1600536809021898

3-exo-Chloro-8-oxabicyclo-[3.2.1]oct-6-ene-2,4-diol chloro-form 0.33-solvate

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 13;65(Pt 7):o1580. doi: 10.1107/S1600536809021898.

Authors

Viktor A Tafeenko¹, Leonid A Aslanov, Marina V Proskurnina, Sergei E Sosonyuk, Dmitrii A Khlevin

Affiliation

¹ Chemistry Department, Moscow State University, 119991 Moscow, Russian Federation.

Abstract

The title compound, 3C(7)H(9)ClO(3)·CHCl(3), crystallizes with mol-ecules of 3-exo-chloro-8-oxabicyclo-[3.2.1]oct-6-ene-2,4-diol (A) and chloro-form in a 3:1 ratio, in the space group R3m. Mol-ecules of A straddle a crystallographic mirror plane, whereas the chloro-form mol-ecules (C and H atoms) lie additionally on the threefold axis. The mol-ecules of A are linked into right- and left-helical chains by means of O-H⋯O hydrogen bonds, thus forming columns running along the c axis. Six inter-penetrated columns form a channel in which the solvent mol-ecules (chloro-form) are located.