[Tris(3,5-diphenyl-pyrazol-yl)hydro-borato]nickel(II) bromide

David J Harding; Phimphaka Harding; Harry Adams

doi:10.1107/S1600536809021606

[Tris(3,5-diphenyl-pyrazol-yl)hydro-borato]nickel(II) bromide

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 13;65(Pt 7):m773. doi: 10.1107/S1600536809021606.

Authors

David J Harding, Phimphaka Harding, Harry Adams

Abstract

In the title tris-(pyrazol-yl)borate (Tp(Ph2)) complex, [NiBr(C(45)H(34)BN(6))], the Ni, Br and B atoms lie on a crystallographic threefold axis and a distorted NiN(3)Br tetra-hedral geometry arises for the metal ion. In the crystal, C-H⋯(C=C) and C-H⋯π inter-actions help to establish the polar crystal packing.