catena-Poly[[diaquacobalt(II)]-bis(μ-3-carboxy-adamantane-1-carboxyl-ato-κO:O)]

Li-Ming Tang; Jia-Hui Xu; Xiao-Yan Han; Wei Xu

doi:10.1107/S1600536809007387

catena-Poly[[diaquacobalt(II)]-bis(μ-3-carboxy-adamantane-1-carboxyl-ato-κO:O)]

Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 6;65(Pt 4):m375. doi: 10.1107/S1600536809007387.

Authors

Li-Ming Tang¹, Jia-Hui Xu, Xiao-Yan Han, Wei Xu

Affiliation

¹ State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Institute of Solid Materials Chemistry, Ningbo University, Ningbo, Zhejiang, 315211, People's Republic of China.

Abstract

In the title compound, [Co(C(12)H(15)O(4))(2)(H(2)O)(2)](n), adjacent Co(II) atoms ( symmetry) are bridged by 3-carboxy-adamantane-1-carboxyl-ate anions, forming a chain running along [001]. Inter-chain O-H⋯O hydrogen bonds link the chains into layers parallel to (100); the layers are further connected via inter-layer hydrogen bonds inter-actions, forming a three-dimensional framework.