Poly[[tris-[μ-2,2'-(butane-1,4-diyl-dithio)bis-(1,3,4-thia-diazole)-κN:N]copper(II)] bis-(perchlorate)]

Pu-Zhou Hu; Jian-Hua Qin; Jian-Ge Wang

doi:10.1107/S1600536809005625

Poly[[tris-[μ-2,2'-(butane-1,4-diyl-dithio)bis-(1,3,4-thia-diazole)-κN:N]copper(II)] bis-(perchlorate)]

Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 21;65(Pt 3):m307. doi: 10.1107/S1600536809005625.

Authors

Pu-Zhou Hu¹, Jian-Hua Qin, Jian-Ge Wang

Affiliation

¹ College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, People's Republic of China.

Abstract

In the title compound, {[Cu(C(8)H(10)N(4)S(4))(3)](ClO(4))(2)}(n), the Cu(II) atom is located on a threefold inversion axis coordinated by six N atoms of symmetry-equivalent 2,2'-(butane-1,4-diyl-dithio)bis-(1,3,4-thia-diazole) ligands in a slightly distorted octa-hedral geometry. Adjacent Cu(II) atoms are linked by the bridging bidentate thia-diazole ligands, which are situated about inversion centers. This leads to the formation of a three-dimensional network structure.