Chlorido{2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III)

Ming-Jie Li; Peng-Fei Yan; Guang-Ming Li; Hong-Feng Li

doi:10.1107/S1600536809005352

Chlorido{2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III)

Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 21;65(Pt 3):m306. doi: 10.1107/S1600536809005352.

Authors

Ming-Jie Li¹, Peng-Fei Yan, Guang-Ming Li, Hong-Feng Li

Affiliation

¹ School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, People's Republic of China.

Abstract

In the title complex, [Mn(C(17)H(16)N(2)O(2))Cl], the Mn(III) ion is coordinated by two O [Mn-O = 1.719 (2) and 1.813 (2) Å] and two N [Mn-N = 1.824 (2) and 1.931 (2) Å] atoms from the tetra-dentate Schiff base ligand and a chloride anion [Mn-Cl = 2.9634 (16) Å] in a square-pyramidal geometry. In the ligand, the two benzene rings form a dihedral angle of 68.06 (5)°.