[1,2-Bis(diphenyl-phosphino)ethane-κP,P'](2-carboxyl-atothio-phenolato-κO,S)nickel(II) methanol solvate

Jinling Miao; Furong Li; Haiyan Chen; Daqi Wang; Yong Nie

doi:10.1107/S1600536808044280

[1,2-Bis(diphenyl-phosphino)ethane-κP,P'](2-carboxyl-atothio-phenolato-κO,S)nickel(II) methanol solvate

Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):m156. doi: 10.1107/S1600536808044280.

Authors

Jinling Miao, Furong Li, Haiyan Chen, Daqi Wang, Yong Nie

Abstract

In the title complex, [Ni(C(7)H(4)O(2)S)(C(26)H(24)P(2))]·CH(3)OH, the nickel(II) centre adopts an approximately square-planar geometry, with the Ni atom coordinating to the S and O atoms of the bidentate thio-salicylate ligand and the two P atoms of the chelating Ph(2)PCH(2)CH(2)PPh(2) ligand. There is hydrogen bonding between the methanol solvent mol-ecule and the carbonyl O atom of the thio-salicylate ligand.