catena-Poly[[[2,6-bis-(pyrazol-1-yl-κN)pyridine-κN](nitrato-κO,O')cadmium(II)]-μ-thio-cyanato-κN:S]

Zhong Nian Yang; Ting Ting Sun

doi:10.1107/S1600536808032297

catena-Poly[[[2,6-bis-(pyrazol-1-yl-κN)pyridine-κN](nitrato-κO,O')cadmium(II)]-μ-thio-cyanato-κN:S]

Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 11;64(Pt 11):m1386. doi: 10.1107/S1600536808032297.

Authors

Zhong Nian Yang, Ting Ting Sun

Abstract

In the title crystal structure, [Cd(NCS)(NO(3))(C(11)H(9)N(5))](n), the unique Cd(II) ion is coordinated in a distorted penta-gonal-bipyramidal environment. The axial thio-cyanate ligands act in a μ(1,3)-bridging mode to connect symmetry-related Cd(II) ions into one-dimensional chains along [010]. In addition, there are inter-molecular C-H⋯O contacts between chains.