Bis[μ-4-hydr-oxy-N'-(4-meth-oxy-2-oxido-benzyl-idene)benzohydrazidato]bis-[pyridine-copper(II)]

Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 31;66(Pt 4):m470. doi: 10.1107/S1600536810011323.

Abstract

In the title compound, [Cu(2)(C(15)H(12)N(2)O(4))(2)(C(6)H(5)N)(2)], each Cu(II) atom is chelated by the tridentate doubly deprotonated Schiff base and a pyridine mol-ecule in a nearly planar environment (r.m.s. deviation for all non-H atoms = 0.107 Å). The metal ions are bridged by one O atom from the symmetry-related Schiff base ligands, forming a centrosymmetric dinuclear copper(II) complex. The dimeric complex is linked to another dimer via weaker Cu-O inter-actions and also O-H⋯N hydrogen bonds.