{1,5,9-Tris[(2S)-2-hydroxy-prop-yl]-1,5,9-triaza-cyclo-dodeca-ne}zinc(II) dinitrate monohydrate

Christoph E Strasser; Jimmy E Y Sumani; Helgard G Raubenheimer; Robert C Luckay

doi:10.1107/S1600536810006410

{1,5,9-Tris[(2S)-2-hydroxy-prop-yl]-1,5,9-triaza-cyclo-dodeca-ne}zinc(II) dinitrate monohydrate

Acta Crystallogr Sect E Struct Rep Online. 2010 Feb 24;66(Pt 3):m327. doi: 10.1107/S1600536810006410.

Authors

Christoph E Strasser¹, Jimmy E Y Sumani, Helgard G Raubenheimer, Robert C Luckay

Affiliation

¹ Department of Chemistry and Polymer Science, University of Stellenbosch, Private Bag X1, Matieland, 7602, South Africa.

Abstract

In the title compound, [Zn(C(18)H(39)N(3)O(3))](NO(3))(2)·H(2)O, the coordination geometry around the central Zn(II) atom is distorted octa-hedral. The hydroxyl groups in the macrocyclic ligand and water mol-ecules are engaged in O-H⋯O hydrogen bonding, which forms two-dimensional corrugated sheets comprising 34-membered rings. Neighbouring sheets are connected by C-H⋯O inter-actions.