Azido-(benzoyl-acetonato-κO,O')[1-phenyl-3-(2-pyridylmethyl-imino)but-1-en-1-olato-κN,N',O]cobalt(III)

Amitabha Datta; Ming-Han Sie; Jui-Hsien Huang; Hon Man Lee

doi:10.1107/S1600536810003338

Azido-(benzoyl-acetonato-κO,O')[1-phenyl-3-(2-pyridylmethyl-imino)but-1-en-1-olato-κN,N',O]cobalt(III)

Acta Crystallogr Sect E Struct Rep Online. 2010 Feb 3;66(Pt 3):m248. doi: 10.1107/S1600536810003338.

Authors

Amitabha Datta¹, Ming-Han Sie, Jui-Hsien Huang, Hon Man Lee

Affiliation

¹ National Changhua University of Education, Department of Chemistry, Changhua, Taiwan 50058.

Abstract

In the title complex, [Co(C(16)H(15)N(2)O)(C(10)H(9)O(2))(N(3))], the Co(II) atom adopts an octa-hedral coordination geometry by a tridentate Schiff base, a bidentate benzoyl-acetonate and an azide ligand. The imine N atom of the tridentate ligand is trans to the benzoyl O atom of the bidentate ligand and the azide ligand is trans to the acetyl O atom of the bidentate ligand. Non-classical intra-molecular C(ar-yl)-H⋯O hydrogen bonds are present in the structure.