catena-Poly[[[diaqua-copper(II)]-bis-(μ(2)-di-4-pyridyl disulfide-κN:N')] bis-(hydrogen phthalate) monohydrate]

Hong-Lin Zhu; Jie Zhang; Jian-Li Lin

doi:10.1107/S1600536810001716

catena-Poly[[[diaqua-copper(II)]-bis-(μ(2)-di-4-pyridyl disulfide-κN:N')] bis-(hydrogen phthalate) monohydrate]

Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 20;66(Pt 2):m185. doi: 10.1107/S1600536810001716.

Authors

Hong-Lin Zhu¹, Jie Zhang, Jian-Li Lin

Affiliation

¹ State Key Laboratory Base of Novel Functional Materials and Preparation Science, Center of Applied Solid State Chemistry Research, Ningbo University, Ningbo, Zhejiang 315211, People's Republic of China.

Abstract

The asymmetric unit of the title compound, {[Cu(C(10)H(8)N(2)S(2))(2)(H(2)O)(2)](C(8)H(5)O(4))(2)·H(2)O}(n), contains one Cu(II) ion, two bridging di-4-pyridyl disulfide (4-DPDS) ligands of the same chirality, two coordinating water mol-ecules, two hydrogen phthalate anions and one uncoordinated water mol-ecule. The polymeric structure consists of two types of polymeric chains, each composed from repeated chiral rhomboids. The Cu(II) ions adopt a distorted octa-hedral coordination geometry and are coordinated by four pyridine N atoms and two water O atoms. The coordinated water mol-ecules and hydrogen phthalate anions are located between the repeated rhomboidal chains, and form hydrogen bonds with the coordinated water mol-ecules.