[N,N'-Bis(2,6-diisopropyl-phen-yl)pentane-2,4-diamine-(1-)-2κN,N']-μ(2)-chlorido-1:2κCl:Cl-chlorido-2κCl-bis-(1,2-di-methoxy-ethane-1κO,O')iron(II)lithium

Rafał Grubba; Lukasz Ponikiewski; Lukasz Tomorowicz; Jerzy Pikies

doi:10.1107/S1600536810018222

[N,N'-Bis(2,6-diisopropyl-phen-yl)pentane-2,4-diamine-(1-)-2κN,N']-μ(2)-chlorido-1:2κCl:Cl-chlorido-2κCl-bis-(1,2-di-methoxy-ethane-1κO,O')iron(II)lithium

Acta Crystallogr Sect E Struct Rep Online. 2010 May 26;66(Pt 6):m707. doi: 10.1107/S1600536810018222.

Authors

Rafał Grubba¹, Lukasz Ponikiewski, Lukasz Tomorowicz, Jerzy Pikies

Affiliation

¹ Chemical Faculty, Gdansk University of Technology, Narutowicza 11/12, Gdansk PL-80233, Poland.

Abstract

In the title compound, [FeLi(C(29)H(41)N(2))Cl(2)(C(4)H(10)O(2))(2)], the Fe(II) atom is coordinated by two N and two Cl atoms, generating a distorted FeN(2)Cl(2) tetra-hedral geometry. Additionally, one of the chloride atoms bridges to a lithium ion, which is solvated by two dimethoxy-ethane mol-ecules and is coordinated in a distorted trigonal-bipyramidal environment. The central Fe, Cl (× 2) and Li atoms are coplanar with a maximum deviation of 0.034 Å.