[N'-(5-Chloro-2-oxidobenzyl-idene-κO)-3-hydr-oxy-2-naphthohydrazidato-κN',O]diphenyl-tin(IV)

See Mun Lee; Kong Mun Lo; Hapipah Mohd Ali; Seik Weng Ng

doi:10.1107/S1600536809050107

[N'-(5-Chloro-2-oxidobenzyl-idene-κO)-3-hydr-oxy-2-naphthohydrazidato-κN',O]diphenyl-tin(IV)

Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 28;65(Pt 12):m1689. doi: 10.1107/S1600536809050107.

Authors

See Mun Lee¹, Kong Mun Lo, Hapipah Mohd Ali, Seik Weng Ng

Affiliation

¹ Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

Abstract

The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)(C(18)H(11)ClN(2)O(3))], is O,N,O'-chelated by the deprotonated Schiff base ligand and further bonded by two phenyl rings in a distorted cis-C(2)SnNO(2) trigonal-bipyramidal geometry [C-Sn-C = 125.7 (2)°]. The two phenyl rings are oriented at a dihedral angle of 55.2 (3)°. Intra-molecular O-H⋯N hydrogen bonding is present in the crystal structure.