Benzyl 3-(10-oxo-9,10-dihydrophenanthren-9-ylidene)dithiocarbazate

Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 28;65(Pt 11):o2853. doi: 10.1107/S160053680904272X.

Abstract

In the title compound, C(22)H(16)N(2)OS(2), the phenanthrene ring is nearly perpendicular to the phenyl ring, making a dihedral angle of 87.2 (2)°. Intra-molecular N-H⋯O inter-actions are present. In the crystal structure, the mol-ecules are linked through inter-molecular C-H⋯O inter-actions. The crystal structure is also stabilized by C-H⋯π inter-actions and weak π-π contacts [centroid-centroid distance = 3.36 (6) Å].