3-Hydr-oxy-N'-[(Z)-(5-methyl-2-fur-yl)methyl-idene]naphthalene-2-carbo-hydrazide

Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 23;65(Pt 11):o2845-6. doi: 10.1107/S1600536809043141.

Abstract

The asymmetric unit of title compound, C(17)H(14)N(2)O(3), contains three independent mol-ecules. In one of these mol-ecules, the 5-methyl-2-furyl group is disordered over two sets of sites with an occupancy ratio of 0.747 (3):0.253 (3). In the two ordered mol-ecules, the furan and naphthalene rings are oriented at dihedral angles of 11.05 (12) and 32.2 (5)°. In the disordered mol-ecule, the furan rings with major and minor occupancies are oriented at dihedral angles of 41.4 (2) and 26.6 (13)°, respectively, with the corresponding naphthalene ring. An intra-molecular O-H⋯O hydrogen bond occurs within each mol-ecule. In the crystal, mol-ecules are linked by N-H⋯O, N-H⋯(N,O) and C-H⋯O inter-actions.