The title compound, [Fe(C(5)H(4)Br)(C(17)H(14)PS)], crystallizes with two practically undistiguishable mol-ecules in the asymmetric unit, which are related by a non-space-group inversion. The ferrocene-1,1'-diyl units exhibit a regular geometry with negligible tilting and balanced Fe-ring centroid distances, and with the attached substituents assuming conformations close to ideal synclinal eclipsed.