{2,2'-[(5-Bromo-pyridine-2,3-di-yl)bis-(nitrilo-methyl-idyne)]diphenolato}chlorido(N,N-dimethyl-formamide)iron(III)

Ning Sheng; Zhonghai Ni

doi:10.1107/S1600536809031432

{2,2'-[(5-Bromo-pyridine-2,3-di-yl)bis-(nitrilo-methyl-idyne)]diphenolato}chlorido(N,N-dimethyl-formamide)iron(III)

Acta Crystallogr Sect E Struct Rep Online. 2009 Sep 12;65(Pt 10):m1202. doi: 10.1107/S1600536809031432.

Authors

Ning Sheng, Zhonghai Ni

Abstract

In the title complex, [Fe(C(19)H(12)BrClN(3)O(2))(C(3)H(7)NO)], the Fe(III) atom is coordinated by an N,N,O,O-tetra-dentate Schiff base ligand and trans coordinated by a chloride anion and the O atom of an N,N-dimethyl-formamide mol-ecule. The resulting geometry is distorted octa-hedral within a ClN(2)O(3) donor set.