Optical modulation of supramolecular assembly of amphiphilic photochromic diarylethene: from nanofiber to nanosphere

Chem Commun (Camb). 2011 Jun 28;47(24):6876-8. doi: 10.1039/c1cc11385b. Epub 2011 May 16.

Abstract

A diarylethene derivative with histamines as side chains was synthesized and the morphology of self-assembled supramolecular architecture can be tuned from nanofiber to nanosphere by photo irradiation. The theoretical calculation and model of the self-assembled nanostructure are presented to illuminate the possible self-assembly mechanism.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Ethane / analogs & derivatives*
  • Ethane / chemical synthesis
  • Ethane / chemistry*
  • Histamine / chemical synthesis
  • Histamine / chemistry*
  • Models, Molecular
  • Nanofibers / chemistry*
  • Nanofibers / ultrastructure
  • Nanospheres / chemistry*
  • Nanospheres / ultrastructure
  • Radiation

Substances

  • Histamine
  • Ethane