Structural interconversion between a chain polymer and a two-dimensional network accompanied by tunable magnetic properties

Chao Chen; Jian-Ke Sun; Wei Li; Chang-Neng Chen; Jie Zhang

doi:10.1039/c0cc05763k

Structural interconversion between a chain polymer and a two-dimensional network accompanied by tunable magnetic properties

Chem Commun (Camb). 2011 Jun 21;47(23):6683-5. doi: 10.1039/c0cc05763k. Epub 2011 May 12.

Authors

Chao Chen¹, Jian-Ke Sun, Wei Li, Chang-Neng Chen, Jie Zhang

Affiliation

¹ State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, PR China.

PMID: 21566805
DOI: 10.1039/c0cc05763k

Abstract

The reaction of 2-hydroxypyrimidine-4,6-dicarboxylic acid (H(3)hpdc) with CuCl(2) under different temperatures gives a chain-like compound [Cu(2)(hpdc)(OH)(H(2)O)(4)]·H(2)O and a layer-like compound [Cu(2)(hpdc)(OH)(H(2)O)], which exhibit structural interconversion and tunable magnetic properties upon dehydration and hydration.