Di-μ-thio-cyanato-κN:S;κS:N-bis-({2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}(thio-cyanato-κN)cadmium)

Nura Suleiman Gwaram; Nurul Azimah Ikmal Hisham; Hamid Khaledi; Hapipah Mohd Ali

doi:10.1107/S1600536811002480

Di-μ-thio-cyanato-κN:S;κS:N-bis-({2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}(thio-cyanato-κN)cadmium)

Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 22;67(Pt 2):m251. doi: 10.1107/S1600536811002480.

Authors

Nura Suleiman Gwaram¹, Nurul Azimah Ikmal Hisham, Hamid Khaledi, Hapipah Mohd Ali

Affiliation

¹ Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

Abstract

In the title complex, [Cd(2)(NCS)(4)(C(13)H(19)N(3)O)(2)], the two Cd(II) ions are bridged by a pair of thio-cyanate N:S-bridging ligands around an inversion center. One terminal thio-cyanate N atom and one N,N',N''-tridentate Schiff base ligand complete a distorted CdN(5)S octa-hedral geometry about each Cd(II) atom. In the crystal, the Schiff base aromatic rings of adjacent mol-ecules are arranged above each other into infinite chains along the a axis with alternate centroid-centroid separations of 3.5299 (13) and 3.7857 (13) Å.