(4,7-Diphenyl-1,10-phenanthroline-κN,N')dimethyl-bis-(thio-cyanato-κN)tin(IV)

Ezzatollah Najafi; Mostafa M Amini; Seik Weng Ng

doi:10.1107/S1600536811001735

(4,7-Diphenyl-1,10-phenanthroline-κN,N')dimethyl-bis-(thio-cyanato-κN)tin(IV)

Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 22;67(Pt 2):m244. doi: 10.1107/S1600536811001735.

Authors

Ezzatollah Najafi, Mostafa M Amini, Seik Weng Ng

Abstract

In the title compound, [Sn(CH(3))(2)(NSC)(2)(C(24)H(16)N(2))], a 1:1 adduct of dimethyl-tin diisothio-cyanate with 4,7-diphenyl-1,10-phenanthroline, the Sn(IV) atom shows a slightly distorted octa-hedral SnC(2)N(4) coordination. The methyl groups are trans to each other in the octa-hedron surrounding the metal atom [C-Sn-C = 176.61 (12)°].