Tris(4-methyl-phen-yl)phosphine selenide

Alfred Muller

doi:10.1107/S1600536810050567

Tris(4-methyl-phen-yl)phosphine selenide

Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 8;67(Pt 1):o45. doi: 10.1107/S1600536810050567.

Author

Alfred Muller¹

Affiliation

¹ Research Centre in Synthesis and Catalysis, Department of Chemistry, University of Johannesburg (APK Campus), PO Box 524, Auckland Park, Johannesburg 2006, South Africa.

Abstract

In the title mol-ecule, C(21)H(21)PSe or PSe(C(7)H(7))(3), the P atom has a distorted PSeC(3) tetra-hedral environment, formed by the Se atom [P=Se = 2.1119 (5) Å] and three aryl rings. Two short intra-molecular C-H⋯Se contacts occur. In the crystal, weak inter-molecular C-H⋯Se inter-actions link the mol-ecules into zigzag double chains propagating in [100]. The previous report of this structure [Zhdanov et al. (1953 ▶). Dokl. Akad. Nauk SSSR (Russ.) (Proc. Nat. Acad. Sci. USSR), 92, 983-985] contained no geometrical data.