Formation energies, chemical bonding, electronic structure, and optical properties of metal-organic frameworks of alkaline earth metals, A-IRMOF-1 (where A = Be, Mg, Ca, Sr, or Ba), have been systemically investigated with DFT methods. The unit cell volumes and atomic positions were fully optimized with the Perdew-Burke-Ernzerhof functional. By fitting the E-V data into the Murnaghan, Birch and Universal equation of states (UEOS), the bulk modulus and its pressure derivative were estimated and provided almost identical results. The data indicate that the A-IRMOF-1 series are soft materials. The estimated bandgap values are all ca. 3.5 eV, indicating a nonmetallic behavior which is essentially metal independent within this A-IRMOF-1 series. The calculated formation energies for the A-IRMOF-1 series are -61.69 (Be), -62.53 (Mg), -66.56 (Ca), -65.34 (Sr), and -64.12 (Ba) kJ mol(-1) and are substantially more negative than that of Zn-based IRMOF-1 (MOF-5) at -46.02 kJ mol(-1). From the thermodynamic point of view, the A-IRMOF-1 compounds are therefore even more stable than the well-known MOF-5. The linear optical properties of the A-IRMOF-1 series were systematically investigated. The detailed analysis of chemical bonding in the A-IRMOF-1 series reveals the nature of the A-O, O-C, H-C, and C-C bonds, i.e., A-O is a mainly ionic interaction with a metal dependent degree of covalency. The O-C, H-C, and C-C bonding interactions are as anticipated mainly covalent in character. Furthermore it is found that the geometry and electronic structures of the presently considered MOFs are not very sensitive to the k-point mesh involved in the calculations. Importantly, this suggests that sampling with Γ-point only will give reliable structural properties for MOFs. Thus, computational simulations should be readily extended to even more complicated MOF systems.