Exclusive enantioselective recognition of glucopyranosides by inherently chiral hemicryptophanes

Chem Commun (Camb). 2011 May 28;47(20):5861-3. doi: 10.1039/c1cc10964b. Epub 2011 Apr 18.

Abstract

Inherently chiral hemicryptophanes were used to complex β- and α-glucoside derivatives with high diastereo- and enantio-selectivity. In most cases, the exclusive recognition by the M-hemicryptophane enantiomers was observed.

MeSH terms

  • Glucosides / chemistry*
  • Polycyclic Compounds / chemistry*
  • Stereoisomerism
  • Thermodynamics

Substances

  • Glucosides
  • Polycyclic Compounds
  • cryptophane