Plexciton dynamics: exciton-plasmon coupling in a J-aggregate-Au nanoshell complex provides a mechanism for nonlinearity

Nano Lett. 2011 Apr 13;11(4):1556-60. doi: 10.1021/nl104352j. Epub 2011 Mar 18.

Abstract

Coherently coupled plasmons and excitons give rise to new optical excitations--plexcitons--due to the strong coupling of these two oscillator systems. Time-resolved studies of J-aggregate-Au nanoshell complexes when the nanoshell plasmon and J-aggregate exciton energies are degenerate probe the dynamical behavior of this coupled system. Transient absorption of the interacting plasmon-exciton system is observed, in dramatic contrast to the photoinduced transmission of the pristine J-aggregate. An additional, transient Fano-shaped modulation within the Fano dip is also observable. The behavior of the J-aggregate-Au nanoshell complex is described by a combined one-exciton and two-exciton state model coupled to the nanoshell plasmon.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Computer Simulation
  • Gold / chemistry*
  • Light
  • Models, Chemical*
  • Nanostructures / chemistry*
  • Nanostructures / ultrastructure
  • Nonlinear Dynamics
  • Particle Size
  • Scattering, Radiation
  • Surface Plasmon Resonance / methods*

Substances

  • Gold