Abstract
A bifunctional imidazolium linker was used for the production of highly crosslinked element organic frameworks by Suzuki-coupling with tetrafunctional boronic acids. The resulting porous materials are good heterogeneous organocatalysts in the N-heterocyclic carbene-catalyzed conjugated umpolung of α,β-unsaturated cinnamaldehyde.
© The Royal Society of Chemistry 2011
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Acrolein / analogs & derivatives*
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Acrolein / chemistry
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Boronic Acids / chemistry*
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Catalysis
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Heterocyclic Compounds / chemical synthesis
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Heterocyclic Compounds / chemistry*
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Imidazoles / chemical synthesis*
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Imidazoles / chemistry
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Methane / analogs & derivatives*
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Methane / chemistry
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Molecular Structure
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Particle Size
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Porosity
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Stereoisomerism
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Surface Properties
Substances
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Boronic Acids
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Heterocyclic Compounds
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Imidazoles
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carbene
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Acrolein
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Methane
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cinnamaldehyde