Dielectric confinement of excitons in type-I and type-II semiconductor nanorods

J Phys Condens Matter. 2011 Jan 12;23(1):015301. doi: 10.1088/0953-8984/23/1/015301. Epub 2010 Dec 6.

Abstract

We theoretically study the effect of the dielectric environment on the exciton ground state of CdSe and CdTe/CdSe/CdTe nanorods. We show that insulating environments enhance the exciton recombination rate and blueshift the emission peak by tens of meV. These effects are particularly pronounced for type-II nanorods. In these structures, the dielectric confinement may even modify the spatial distribution of the electron and hole charges. A critical electric field is required to separate electrons from holes, whose value increases with the insulating strength of the surroundings.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Cadmium Compounds / chemistry
  • Electric Impedance
  • Electrons
  • Nanotubes / chemistry*
  • Selenium Compounds / chemistry
  • Semiconductors*
  • Tellurium / chemistry

Substances

  • Cadmium Compounds
  • Selenium Compounds
  • cadmium selenide
  • Tellurium
  • cadmium telluride