Catalytic hydrodefluorination of pentafluorobenzene by [Ru(NHC)(PPh3)2(CO)H2]: a nucleophilic attack by a metal-bound hydride ligand explains an unusual ortho-regioselectivity

Angew Chem Int Ed Engl. 2011 Mar 14;50(12):2783-6. doi: 10.1002/anie.201006789. Epub 2011 Feb 17.
No abstract available

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Catalysis
  • Coordination Complexes / chemistry*
  • Fluorine / chemistry*
  • Ligands
  • Methane / analogs & derivatives
  • Methane / chemistry
  • Quantum Theory
  • Ruthenium / chemistry*
  • Stereoisomerism

Substances

  • Coordination Complexes
  • Ligands
  • carbene
  • Fluorine
  • Ruthenium
  • Methane