Enhanced performance of the dye-sensitized solar cells with phenothiazine-based dyes containing double D-A branches

Org Lett. 2011 Apr 1;13(7):1610-3. doi: 10.1021/ol2000167. Epub 2011 Mar 3.

Abstract

Double donor-acceptor (D-A) branched dyes (DBD) with a phenothiazine unit as electron donor and a 2-cyanoacrylic acid unit as electron acceptor were synthesized and used as sensitizers for solar cells (DSSCs). The conversion efficiency of the DSSCs amounts up to 4.22% (2.91% for the single D-A branched dye) under AM 1.5 G irradiation. The results show that the performance of DSSCs can be effectively enhanced by the cooperation of two donor-acceptor containing branches in one molecule of the dyes.