Synthesis and cross-coupling of sulfonamidomethyltrifluoroborates

Org Lett. 2011 Apr 1;13(7):1694-7. doi: 10.1021/ol200202g. Epub 2011 Mar 2.

Abstract

Sulfonamidomethyltrifluoroborates were successfully synthesized and cross-coupled with a wide range of aryl and heteroaryl chlorides, allowing the construction of a sulfonamidomethyl aryl linkage through a new disconnection, thus offering a new way to access such structurally interesting motifs.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amides / chemistry*
  • Boric Acids / chemical synthesis*
  • Fluorine Compounds / chemical synthesis*
  • Methylation
  • Molecular Structure
  • Sulfur Compounds / chemical synthesis*

Substances

  • Amides
  • Boric Acids
  • Fluorine Compounds
  • Sulfur Compounds
  • boric acid