Condensed tantalaborane clusters: synthesis and structures of [(Cp*Ta)2B5H7{Fe(CO)3}2] and [(Cp*Ta)2B5H9{Fe(CO)3}4]

Shubhankar Kumar Bose; K Geetharani; Babu Varghese; Sundargopal Ghosh

doi:10.1021/ic102235p

Condensed tantalaborane clusters: synthesis and structures of [(CpTa)2B5H7{Fe(CO)3}2] and [(CpTa)2B5H9{Fe(CO)3}4]

Inorg Chem. 2011 Mar 21;50(6):2445-9. doi: 10.1021/ic102235p. Epub 2011 Feb 22.

Authors

Shubhankar Kumar Bose¹, K Geetharani, Babu Varghese, Sundargopal Ghosh

Affiliation

¹ Department of Chemistry, Indian Institute of Technology Madras, Chennai 600 036, India.

PMID: 21341731
DOI: 10.1021/ic102235p

Abstract

The reaction of [(Cp*Ta)(2)B(4)H(9)(μ-BH(4))] (1; Cp* = η(5)-C(5)Me(5)) with [Fe(2)(CO)(9)] in hexane yielded [(Cp*Ta)(2)B(5)H(7){Fe(CO)(3)}(2)] (2) and [(Cp*Ta)(2)B(5)H(9){Fe(CO)(3)}(4)] (3) in moderate yield. Cluster 2 represents the first example of a bicapped pentagonal-bipyramidal metallaborane with a deformed equatorial plane, and 3 can be described as a fused cluster in which two pentagonal-bipyramidal units are fused through a common 3-vertex triangular face. Compounds 2 and 3 have been characterized by mass spectrometry and IR, (1)H, (11)B, and (13)C NMR spectroscopy, and the geometric structures were unequivocally established by crystallographic analysis.