Abstract
A new method for the preparation of a wide range of branched allylic esters from terminal alkynes that proceeds via a redox-neutral propargylic CH activation employing a rhodium(I)/DPEphos catalyst is reported.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Alkynes / chemistry*
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Allyl Compounds / chemical synthesis*
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Allyl Compounds / chemistry
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Carboxylic Acids / chemistry*
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Catalysis
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Esters / chemical synthesis*
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Esters / chemistry
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Molecular Structure
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Oxidation-Reduction
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Rhodium / chemistry*
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Stereoisomerism
Substances
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Alkynes
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Allyl Compounds
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Carboxylic Acids
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Esters
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Rhodium