A concise total synthesis of (±)-cipadonoid B from synthetic azedaralide

Jonathan M Faber; Craig M Williams

doi:10.1039/c0cc04698a

A concise total synthesis of (±)-cipadonoid B from synthetic azedaralide

Chem Commun (Camb). 2011 Feb 28;47(8):2258-60. doi: 10.1039/c0cc04698a. Epub 2011 Jan 24.

Authors

Jonathan M Faber¹, Craig M Williams

Affiliation

¹ School of Chemistry and Molecular Biosciences, University of Queensland, Brisbane, 4072, Queensland, Australia.

PMID: 21258734
DOI: 10.1039/c0cc04698a

Abstract

The tetranortriterpene cipadonoid B was efficiently constructed from synthetic azedaralide in a one-pot cascade, via the underutilised ketal-Claisen rearrangement.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Crystallography, X-Ray
Limonins / chemical synthesis*
Limonins / chemistry
Molecular Conformation
Stereoisomerism
Triterpenes / chemical synthesis
Triterpenes / chemistry*

Substances

Limonins
Triterpenes