Abstract
Trinuclear rare-earth metal complexes [M₃(taciH₋₃)₂](3+) (M = La(3+), Y(3+)), based on a rigid polyamino-polyalcohol ligand 1,3,5-triamino-1,3,5-trideoxy-cis-inositol (taci), are proven to be efficient catalysts for the hydrolysis of 2-hydroxypropyl-4-nitrophenyl phophate (HPNP), a commonly used RNA model system.
MeSH terms
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Catalysis
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Coordination Complexes / chemistry*
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Hydrogen-Ion Concentration
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Hydrolysis
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Inositol / analogs & derivatives*
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Inositol / chemistry
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Kinetics
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Metals, Rare Earth / chemistry*
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Organophosphates
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Organophosphorus Compounds / chemistry
Substances
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1,3,5-triamino-1,3,5-trideoxy-inositol
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2-(hydroxypropyl)-4-nitrophenyl phosphate
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Coordination Complexes
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Metals, Rare Earth
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Organophosphates
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Organophosphorus Compounds
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Inositol