Dioxidobis(pentane-2,4-dionato-κO,O')(pyridine-4-carbaldehyde oxime-κN)uranium(VI)

Takeshi Kawasaki; Takafumi Kitazawa

doi:10.1107/S1600536808012889

Dioxidobis(pentane-2,4-dionato-κO,O')(pyridine-4-carbaldehyde oxime-κN)uranium(VI)

Acta Crystallogr Sect E Struct Rep Online. 2008 May 10;64(Pt 6):m788. doi: 10.1107/S1600536808012889.

Authors

Takeshi Kawasaki, Takafumi Kitazawa

Abstract

The title compound, [U(C(5)H(7)O(2))(2)O(2)(C(6)H(6)N(2)O)], exhibits a penta-gonal-bipyramidal coordination geometry around the U(VI) atom, involving two bidentate acetyl-acetonate ions and the pyridine ring of the pyridine-4-carbaldehyde oxime ligand. Hydrogen bonds exist between the OH group of the pyridine-4-carbaldehyde oxime ligand and the two O atoms of the acetyl-acetonate ions.